Preparation of Nano Zinc Oxide with Polycaprolactone and Evaluation of Electrospun Scaffold Composite

  • Hassan Khudher Naji Department Science, College of Basic Education, University of Babylon, Hilla-Iraq
Keywords: Nanofibers, ZnO nanoparticles, Electrospinning, Scaffolds, Polycaprolactone

Abstract

The creation and development of medical polymer polycaprolactone (PCL) and zinc oxide nanofibers (ZnO NPs) and their catalytic activity against dangerous bacteria and germs are the most important electrospinning techniques in this work. 2% and 3% were applied in addition to the electrospinning process. Pure polymer divided by the weight of zinc oxide nanoparticles (PCL). Scanning electron microscopy (SEM), AFM surface roughness, X-ray diffraction (XRD), material crystallization, FT-IR spectroscopy, and the nature of the interaction between nanoparticles (ZnO) and pure polymer were used to determine the fiber diameter. This reaction shows catalytic properties and mechanical stability through mechanical property testing. In addition to how viscosity increases with increasing concentration. High porosity is provided by water angle testing and good adhesion by these scaffolds. These concentrations can be used as an antibacterial and antibacterial agent.

Downloads

Download data is not yet available.

References

Essa, Wafa K., et al. "Nanofiber-based face masks and respirators as covid-19 protection: A review." Membranes 11.4 (2021): 250

Zhou, Yangjian, et al. "Electrospun nanofiber membranes for air filtration: A review." Nanomaterials 12.7 (2022): 1077.

Lu, Tao, et al. "Multistructured electrospun nanofibers for air filtration: a review." ACS Applied Materials & Interfaces 13.20 (2021): 23293-23313.

Shen, Hongchen, et al. "Electrospun nanofibrous membranes for controlling airborne viruses: Present status, standardization of aerosol filtration tests, and future development." ACS Environmental Au 2.4 (2022): 290-309.

O’Dowd, Kris, et al. "Face masks and respirators in the fight against the COVID-19 pandemic: A review of current materials, advances and future perspectives." Materials 13.15 (2020): 3363.

Lepot, Nadia, et al. "Influence of incorporation of ZnO nanoparticles and biaxial orientation on mechanical and oxygen barrier properties of polypropylene films for food packaging applications." Journal of applied polymer science 120.3 (2011): 1616-1623.

Woodruff, Maria Ann, and Dietmar Werner Hutmacher. "The return of a forgotten polymer—Polycaprolactone in the 21st century." Progress in polymer science 35.10 (2010): 1217-1256.

Dwivedi, Ruby, et al. "Polycaprolactone as biomaterial for bone scaffolds: Review of literature." Journal of oral biology and craniofacial research 10.1 (2020): 381-388.

Chang, Seo Hee, et al. "Fast degradable polycaprolactone for drug delivery." Biomacromolecules 19.6 (2018): 2302-2307.

Lopez-Figueras, Laura, Nuria Navascues, and Silvia Irusta. "Polycaprolactone/mesoporous silica MCM-41 composites prepared by in situ polymerization." Particuology 30 (2017): 135-143.

Das, Rashmita, A. J. Pattanayak, and Sarat K. Swain. "Polymer nanocomposites for sensor devices." Polymer-based nanocomposites for energy and environmental applications. Woodhead Publishing, 2018. 205-218.

Hejazi, Vahid, Konstantin Sobolev, and Michael Nosonovsky. "From superhydrophobicity to icephobicity: forces and interaction analysis." Scientific reports 3.1 (2013): 1-6.

Farhadi, Shahram, Masoud Farzaneh, and Sergei A. Kulinich. "Anti-icing performance of superhydrophobic surfaces." Applied Surface Science 257.14 (2011): 6264-6269.

Zhang, Dawei, et al. "Superhydrophobic surfaces for corrosion protection: a review of recent progresses and future directions." Journal of Coatings Technology and Research 13.1 (2016): 11-29.

Su, Fenghua, and Kai Yao. "Facile fabrication of superhydrophobic surface with excellent mechanical abrasion and corrosion resistance on copper substrate by a novel method." ACS applied materials & interfaces 6.11 (2014): 8762-8770.

She, Z.; Li, Q.; Wang, Z.; Li, L.; Chen, F.; Zhou, J. Researching the fabrication of anticorrosion superhydrophobic surface on magnesium alloy and its mechanical stability and durability. Chem. Eng. J. 2013, 228, 415–424.

Jiang, L.; Zhao, Y.; Zhai, J. A Lotus-Leaf-like Superhydrophobic Surface: A Porous Microsphere/Nanofiber Co22.

Horcas, I.; Fernandez, R.; Gomez, J.; Colchero, J.; Gomez, J.; Baro, A.A. A software for scanning probe microscopy and a tool for nanotechnology. Rev. Sci. Instrum. 2007, 78, 013705.

Ali, A., et al., Antibacterial bi-layered polyvinyl alcohol (PVA)-chitosan blend nanofibrous mat loaded with Azadirachta indica (neem) extract. International journal of biological macromolecules, 2019. 138: p. 13-20.mposite Film Prepared by Electrohydrodynamics. Angew. Chem. 2004, 43, 4338–4341.

Guo, Z.; Liu, W.; Su, B.-L. Superhydrophobic surfaces: From natural to biomimetic to functional. J. Colloid Interface Sci. 2011, 353, 335–355.

Kahdim, Qasim Shakir, et al. "Fabrication of a polycaprolactone/Chitosan nanofibrous scaffold loaded with nigella sativa extract for biomedical applications." BioTech 12.1 (2023): 19.

Hassan, M.I.; Sultana, N. Characterization, drug loading and antibacterial activity of nanohydroxyapatite/polycaprolactone (nHA/PCL) electrospun membrane. 3 Biotech 2017, 7, 1–9.

Zamani, F.; Amani-Tehran, M.; Latifi, M.; Shokrgozar, M.A. The influence of surface nanoroughness of electrospun PLGA nanofibrous scaffold on nerve cell adhesion and proliferation. J. Mater. Sci. Med. 2013, 24, 1551–156

Karim, A.M.; Kavehpour, H.P. Effect of viscous force on dynamic contact angle measurement using Wilhelmy plate method. Colloids Surf. A Physicochem. Eng. Asp. 2018, 548, 54–60

El Saeed, Ashraf M., M. Abd El-Fattah, and Ahmed M. Azzam. "Synthesis of ZnO nanoparticles and studying its influence on the antimicrobial, anticorrosion and mechanical behavior of polyurethane composite for surface coating." Dyes and Pigments 121 (2015): 282-289.

Venugopal, Jayarama Reddy, et al. "Nanobioengineered electrospun composite nanofibers and osteoblasts for bone regeneration." Artificial organs 32.5 (2008): 388-397.

Augustine, Robin, et al. "Electrospun polycaprolactone/ZnO nanocomposite membranes as biomaterials with antibacterial and cell adhesion properties." Journal of Polymer Research 21.3 (2014): 1-17.

Augustine, Robin, et al. "Electrospun polycaprolactone/ZnO nanocomposite membranes as biomaterials with antibacterial and cell adhesion properties." Journal of Polymer Research 21 (2014): 1-17.

Kawata, Koji, Masato Osawa, and Satoshi Okabe. "In vitro toxicity of silver nanoparticles at noncytotoxic doses to HepG2 human hepatoma cells." Environmental science & technology 43.15 (2009): 6046-6051.

Kahdim, Qasim Shakir, et al. "Fabrication of a polycaprolactone/Chitosan nanofibrous scaffold loaded with nigella sativa extract for biomedical applications." BioTech 12.1 (2023): 19.

Saati, SAA AL, et al. "Electrospinning for Creation of Zinc Oxide/Poly (methyl methacrylate) Nanofiber Scaffolds." IOP Conference Series: Earth and Environmental Science. Vol. 1325. No. 1. IOP Publishing, 2024.

Rasheed, Maher Hassan, et al. "Synthesis and evaluation structural, thermal and electrical properties for PCL/TiO2 nanocomposites." Transactions on Electrical and Electronic Materials 26.1 (2025): 37-47.

Published
2025-12-12
How to Cite
Naji , H. K. (2025). Preparation of Nano Zinc Oxide with Polycaprolactone and Evaluation of Electrospun Scaffold Composite. Central Asian Journal of Theoretical and Applied Science, 7(1), 69-76. https://doi.org/10.51699/cajotas.v7i1.1634
Section
Articles